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Graphene-wrapped sulfur/metal organic framework-derived microporous carbon composite for lithium sulfur batteries

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dc.contributor.authorChen, Renjie
dc.contributor.authorZhao, Teng
dc.contributor.authorTian, Tian
dc.contributor.authorCao, Shuai
dc.contributor.authorCoxon, Paul
dc.contributor.authorXi, Kai
dc.contributor.authorFairen-Jimenez, David
dc.contributor.authorKumar, Ramachandran
dc.contributor.authorCheetham, Anthony
dc.contributor.otherOrganic Synthesis (ORSY)
dc.contributor.otherMolecular Spectroscopy (MolSpec)
dc.date.accessioned2019-04-26T08:57:03Z
dc.date.available2019-04-26T08:57:03Z
dc.date.issued16/12/14
dc.descriptionA three-dimensional hierarchical sandwich-type graphene sheet-sulfur/carbon (GSS/CZIF8-D) composite for use in a cathode for a lithium sulfur (Li-S) battery has been prepared by an ultrasonic method. The microporous carbon host was prepared by a one-step pyrolysis of Zeolitic Imidazolate Framework-8 (ZIF-8), a typical zinccontaining metal organic framework (MOF), which offers a tunable porous structure into which electro-active sulfur can be diffused. The thin graphene sheet, wrapped around the sulfur/zeolitic imidazolate framework-8 derived carbon (S/CZIF8-D) composite, has excellent electrical conductivity and mechanical flexibility, thus facilitating rapid electron transport and accommodating the changes in volume of the sulfur electrode. Compared with the S/CZIF8-D sample, Li-S batteries with the GSS/CZIF8-D composite cathode showed enhanced capacity, improved electrochemical stability, and relatively high columbic efficiency by taking advantage of the synergistic effects of the microporous carbon from ZIF-8 and a highly interconnected graphene network. Our results demonstrate that a porous MOF-derived scaffold with a wrapped graphene conductive network structure is a potentially efficient design for a battery electrode that can meet the challenge arising from low conductivity and volume change
dc.identifier.urihttps://demo7.dspace.org/handle/123456789/446
dc.languageen
dc.publisherAmerican Institute of Physics Publishing
dc.titleGraphene-wrapped sulfur/metal organic framework-derived microporous carbon composite for lithium sulfur batteries
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